Enzymatic hydrolysis of chitosan. Biological activity of the polymer and its hydrolysates

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A. Falcón

Abstract

Chitosan is a chitin-derived desacetylate, a
polymer of N-acetil-Glucosamine that is extracted from the
exoskeleton of the crustaceans. Both polymers as well as their
oligomers have proved to protect several species of plants
against fungal diseases by means of the induction of defensive
mechanisms that stop the advance of the pathogen in the
vegetable and by direct action of pathogenic fungi growth
inhibition. In this work, the hydrolysis of chitosan with Pectinex
Ultra SPL (Novozymes) was carried out and the course of the
reaction was monitored by determining the intrinsic viscosity
of the solution as well as the increment of reducing sugars
during the reaction time. The analysis of hydrolysis results
allowed to suggest a remarkable endo-chitosanase character
for the Pectinex enzymatic pool. Additionally, the activity of in
vitro growth inhibition of the pathogen Phytophthora
parasitica and the inducing chitinase activity in soybean plants
was comparatively studied, using the native chitosan and their
enzymatic hydrolysates of two and 10 hours. A bigger growth
inhibition of P. parasitica was observed in the case of
hydrolysates regarding the native chitosan, as well as a higher
induction of chitinase activity in soybean plants previously
treated with the 10 hour-hydrolysate. Results are discussed
concerning the importance of GP in the antifungal activity and
signal perception that induces soybean plant defense response,
taking into account the increment of the number of fragments
by means of the hydrolysis.

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How to Cite
Falcón, A. (2013). Enzymatic hydrolysis of chitosan. Biological activity of the polymer and its hydrolysates. Cultivos Tropicales, 25(2), 81–86. Retrieved from https://ediciones.inca.edu.cu/index.php/ediciones/article/view/511
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Original Article